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Efficient Photoelectrochemical Water Splitting by g-C3N4/TiO2 Nanotube Array Heterostructures
Nano-Micro Letters ( IF 31.6 ) Pub Date : 2018-02-09 , DOI: 10.1007/s40820-018-0192-6
Changhai Liu , Fang Wang , Jin Zhang , Ke Wang , Yangyang Qiu , Qian Liang , Zhidong Chen

Well-ordered TiO2 nanotube arrays (TNTAs) decorated with graphitic carbon nitride (g-C3N4) were fabricated by anodic oxidization and calcination process. First, TNTAs were prepared via the anodic oxidation of Ti foil in glycerol solution containing fluorinion and 20% deionized water. Subsequently, g-C3N4 film was hydrothermally grown on TNTAs via the hydrogen-bonded cyanuric acid melamine supramolecular complex. The results showed that g-C3N4 was successfully decorated on the TNTAs and the g-C3N4/TNTAs served as an efficient and stable photoanode for photoelectrochemical water splitting. The facile deposition method enables the fabrication of efficient and low-cost photoanodes for renewable energy applications.
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中文翻译:

通过gC进行的高效光电化学水分解3ñ4/钛2个 纳米管阵列异质结构

通过阳极氧化和煅烧工艺制备了装饰有石墨氮化碳(gC 3 N 4)的有序TiO 2纳米管阵列(TNTA)。首先,通过在含有氟离子和20%去离子水的甘油溶液中对Ti箔进行阳极氧化来制备TNTA。随后,通过氢键合的氰尿酸三聚氰胺超分子络合物在TNTA上水热生长gC 3 N 4膜。结果表明GC 3 Ñ 4被装饰成功对TNTAs和GC 3 Ñ 4/ TNTAs是用于光电化学水分解的高效,稳定的光阳极。简便的沉积方法能够制造可再生能源应用中的高效,低成本的光阳极。
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更新日期:2018-02-09
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