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Enantioselective Synthesis of Nonracemic Geminal Silylboronates by Pt-Catalyzed Hydrosilylation
ACS Catalysis ( IF 11.3 ) Pub Date : 2018-02-23 00:00:00 , DOI: 10.1021/acscatal.8b00221
Adam A. Szymaniak 1 , Chenlong Zhang 1 , John R. Coombs 1 , James P. Morken 1
Affiliation  

A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates is described. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral nonracemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis.

中文翻译:


Pt 催化硅氢加成对映选择性合成非外消旋偕甲硅烷基硼酸酯



描述了烯基硼酸酯的 Pt 催化对映选择性氢化硅烷化。该反应具有高区域选择性和对映选择性,为制备手性非外消旋偕甲硅烷基硼酸酯提供了便捷的途径。这些化合物是立体选择性合成中有用的试剂。
更新日期:2018-02-23
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