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Chiral bis(phthalocyaninato) terbium double-decker compounds with enhanced single-ion magnetic behavior†
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2018-02-23 00:00:00 , DOI: 10.1039/c8qi00066b
Kang Wang 1, 2, 3, 4, 5 , Fang Ma 5, 6, 7, 8 , Dongdong Qi 1, 2, 3, 4, 5 , Xin Chen 1, 2, 3, 4, 5 , Yuxiang Chen 1, 2, 3, 4, 5 , Yan-Cong Chen 9, 10, 11, 12, 13 , Hao-Ling Sun 5, 6, 7, 8 , Ming-Liang Tong 9, 10, 11, 12, 13 , Jianzhuang Jiang 1, 2, 3, 4, 5
Affiliation  

Chiral binaphthyl substituents were incorporated onto the phthalocyanine periphery in both homoleptic and heteroleptic bis(phthalocyaninato) terbium single-ion magnets, which exhibit blocking temperatures as high as 15 K and 28 K, respectively, providing an alternative method towards enhancing the magnetic behavior.

中文翻译:

具有增强的单离子磁性能的手性双(酞菁基)ter双层化合物

手性联萘取代基被掺入均化和杂化的双(酞菁基)single单离子磁体的酞菁外围,它们分别具有高达15 K和28 K的阻断温度,为增强磁性能提供了另一种方法。
更新日期:2018-02-23
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