N₂ fixation by the electrocatalytic nitrogen reduction reaction (NRR) under ambient conditions is regarded as a potential approach to achieve NH₃ production, which still heavily relies on the Haber–Bosch process at the cost of huge energy and massive production of CO₂. A noble‐metal‐free Bi₄V₂O₁₁/CeO₂ hybrid with an amorphous phase (BVC‐A) is used as the cathode for electrocatalytic NRR. The amorphous Bi₄V₂O₁₁ contains significant defects, which play a role as active sites. The CeO₂ not only serves as a trigger to induce the amorphous structure, but also establishes band alignment with Bi₄V₂O₁₁ for rapid interfacial charge transfer. Remarkably, BVC‐A shows outstanding electrocatalytic NRR performance with high average yield (NH₃: 23.21 μg h⁻¹ mg⁻¹_cat., Faradaic efficiency: 10.16 %) under ambient conditions, which is superior to the Bi₄V₂O₁₁/CeO₂ hybrid with crystalline phase (BVC‐C) counterpart.

中文翻译：

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一种能够在环境条件下固氮的非晶态无贵金属电催化剂

在环境条件下通过电催化氮还原反应（NRR）固定N ₂被认为是实现NH ₃生产的潜在方法，该方法仍大量依赖Haber-Bosch工艺，但要消耗大量能量和大量生产CO ₂。具有无定形相（BVC-A）的无贵金属Bi ₄ V ₂ O ₁₁ / CeO ₂杂化物用作电催化NRR的阴极。非晶态Bi ₄ V ₂ O ₁₁包含明显的缺陷，这些缺陷起着活性位点的作用。首席执行官₂不仅用作引发非晶结构的触发器，而且还与Bi ₄ V ₂ O ₁₁建立能带对准，以实现快速的界面电荷转移。值得注意的是，BVC-A在环境条件下具有出色的电催化NRR性能，平均收率高（NH ₃：23.21μgh ^-1  mg ^-1 _cat。，法拉第效率：10.16％），优于Bi ₄ V ₂ O ₁₁ / CeO ₂杂化物与结晶相（BVC-C）对应物。