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POCl3‐Promoted Trifluoromethylthiolation‐Based Vicinal Bifunctionalization of Indoles with CF3SO2Na
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-05-11 , DOI: 10.1002/ejoc.201800249 Dong-Wei Sun 1 , Xu Jiang 2 , Min Jiang 1 , Yun Lin 2 , Jin-Tao Liu 1
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-05-11 , DOI: 10.1002/ejoc.201800249 Dong-Wei Sun 1 , Xu Jiang 2 , Min Jiang 1 , Yun Lin 2 , Jin-Tao Liu 1
Affiliation
Direct trifluoromethylthiolation‐based vicinal bifunctionalization of indoles with sodium trifluoromethanesulfinate in the presence of phosphorus oxychloride was achieved, which affords another functional group (chloro or bromo) for further transformation.
中文翻译:
POCl3促进的含CF3SO2Na的吲哚基于三氟甲基硫醇化的邻位双功能化
在三氯氧化亚磷存在下,用三氟甲亚磺酸钠直接对吲哚进行基于三氟甲基硫醇化的邻位双官能化,从而提供了另一个官能团(氯或溴)进行进一步转化。
更新日期:2018-05-11
中文翻译:
POCl3促进的含CF3SO2Na的吲哚基于三氟甲基硫醇化的邻位双功能化
在三氯氧化亚磷存在下,用三氟甲亚磺酸钠直接对吲哚进行基于三氟甲基硫醇化的邻位双官能化,从而提供了另一个官能团(氯或溴)进行进一步转化。