The resultant energy of solvent H-O bond exothermic elongation by O:⇔:O repulsion, featured at <3100 cm^-1, and the solute H-O bond endothermic contraction by bond-order-deficiency, at 3610 cm^-1, heats up the (Li, Na, K)OH solutions. The solution temperature increases linearly with the number fraction of the ordinary O:H-O bonds transiting into their hydration states. The elongated H-O bond emits >150% the O:H cohesive energy of 0.095 eV that caps the energy dissipating by molecular motion, thermal fluctuation, diffusion, and even evaporation. Therefore, the intramolecular H-O bond relaxation dictates the OH^- solvation bonding thermodynamics and the performance of basic solutions.

溶剂HO键因O：⇔：O排斥而放热伸长的合成能量在<3100 cm ^-1处发生，溶质HO键通过键序缺陷在3610 cm ^-1处发生吸热收缩，使（Li ，Na，K）OH溶液。溶液温度随着普通O：HO键的数量分数转变为水合状态而线性增加。细长的HO键发出的O：H内聚能为0.095 eV，大于150％，该内能限制了通过分子运动，热涨落，扩散甚至蒸发而耗散的能量。因此，分子内HO键松弛使然的OH ^-溶剂化结合热力学和碱性溶液的性能。