Catalysis Today ( IF 5.2 ) Pub Date : 2018-02-21 , DOI: 10.1016/j.cattod.2018.02.029 Yangfan Li , Linlin Wang , Zhaolong Li , Yueli Liu , Zhuoyin Peng , Min Zhou , Chao Zhang , Wei Jin
In the present work, V2O5 microspheres with the diameters ranging from 1 to 2 μm are prepared by a facile hydrothermal progress, and then V2O5@TiO2 core-shell microspheres are successfully synthesized by a solution method. It is found that the light absorption intensity of V2O5@TiO2 core-shell microspheres is greatly enhanced compared with those of V2O5 microspheres and P25 in UV and visible light ranges. The photodegradation rate towards gaseous benzene of V2O5@TiO2-20% core-shell microspheres is the best one, and it will increase from 27.8% and 10% (pure V2O5 microspheres) to be 100% and 71.8% after 75 min’ irradiation under UV and visible light irradiation, respectively. The reason lies in the fact that the formation of V2O5@TiO2 core-shell microspheres may favor for the light absorption as well as the effective separation of the photoexcited electrons and holes.
中文翻译:
V 2 O 5 @TiO 2核壳微球的合成及其对气态苯的光催化性能
在本工作中,通过简便的水热工艺制备了直径为1至2μm的V 2 O 5微球,然后通过溶液法成功合成了V 2 O 5 @TiO 2核壳微球。发现在紫外和可见光范围内,V 2 O 5 @TiO 2核壳微球的光吸收强度比V 2 O 5微球和P25的光吸收强度大大提高。V 2 O 5 @TiO 2对气态苯的光降解速率-20%的核壳微球是最好的,在紫外线和可见光照射75分钟后,它将从27.8%和10%(纯V 2 O 5微球)分别增加到100%和71.8%。 。原因在于,V 2 O 5 @TiO 2核-壳微球的形成可能有利于光吸收以及光激发电子和空穴的有效分离。