Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-02-21 , DOI: 10.1016/j.cplett.2018.02.053 Liudmila E. Shmukler , Yuliya A. Fadeeva , Ekaterina V. Glushenkova , Van Thuc Nguyen , Liubov P. Safonova
The proton-conducting gel electrolytes (PCGEs) based on PMMA, PVdF or PVdF-HFP doped with solutions of phosphonic acid or ammonium based protic ionic liquids (PILs) in DMF have been synthesized. Rather high values of the conductivity (10−4 – 10−3 S cm−1) have been reached at low dopant concentrations (up to 1 mol l-1). The influence of the nature of both polymeric matrix and dopant as well as dopant concentration on the conductivity values was discussed. It was established that the dependence of conductivity on the nature of dopant, but not the polymeric matrix, was more pronounced.
中文翻译:
掺杂有膦酸或质子离子液体的凝胶聚合物电解质的电导率
已经合成了基于PMMA,PVdF或PVdF-HFP的质子传导凝胶电解质(PCGE),掺杂了膦酸或铵基质子离子液体(PIL)在DMF中的溶液。电导率的相当高的值(10 -4 - 10 -3小号厘米-1)已经在低掺杂剂浓度已经达到(最多1摩尔升-1)。讨论了聚合物基体和掺杂剂的性质以及掺杂剂浓度对电导率值的影响。已经确定,电导率对掺杂剂的性质而不是聚合物基体的依赖性更加明显。