Front Cover: Electrochemical Investigation of the Kinetics of Chloride Substitution upon Reduction of [Ru(porphyrin)(NO)Cl] Complexes in Tetrahydrofuran (ChemElectroChem 6/2018),ChemElectroChem

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Front Cover: Electrochemical Investigation of the Kinetics of Chloride Substitution upon Reduction of [Ru(porphyrin)(NO)Cl] Complexes in Tetrahydrofuran (ChemElectroChem 6/2018)
ChemElectroChem ( IF 3.5 ) Pub Date : 2018-02-21 , DOI: 10.1002/celc.201800218
Jeremy R. Zink _{1,

2} , Erwin G. Abucayon ₂ , Anthony R. Ramuglia ₁ , Arghavan Fadamin ₁ , James E. Eilers ₁ , George B. Richter-Addo ₂ , Michael J. Shaw ₁

Affiliation

The Front Cover shows cartoons of species formed during cyclic voltammetry (CV) analysis of [Ru(porphyrin)(NO)Cl] in tetrahydrofuran. The initial redox‐induced reversible solvent‐for‐chloride metathesis shown in the reaction at the top occurs at diffusion‐limited rates. This reaction, and others, were elucidated by analysis and simulation of CV data, chemical reduction, and IR spectroelectrochemistry. Subsequent electron‐transfer reactions occur at the thus‐formed solvento species, which features a bent NO ligand. More information can be found in the Article by J. R. Zink et al. on page 861 in Issue 6, 2018 (DOI: 10.1002/celc.201701001).

中文翻译：

封面：四氢呋喃中[Ru（卟啉）（NO）Cl]配合物还原后氯化物取代动力学的电化学研究（ChemElectroChem 6/2018）

封面显示了四氢呋喃中[Ru（卟啉）（NO）Cl]的循环伏安（CV）分析过程中形成的物种的动画片。反应顶部显示的最初的氧化还原诱导的可逆氯化物易位反应发生在扩散受限的速率下。通过分析和模拟CV数据，化学还原和IR光谱电化学，阐明了该反应及其他反应。随后形成的溶剂分子发生电子转移反应，该溶剂具有弯曲的NO配体。可以在J. R. Zink等人的《文章》中找到更多信息。就在第6期，2018页861（：10.1002 / celc.201701001 DOI）。

更新日期：2018-02-21

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