Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage,Accounts of Chemical Research

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Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-02-19 00:00:00 , DOI: 10.1021/acs.accounts.7b00478
Lisa M. Housel ₁ , Lei Wang ₁ , Alyson Abraham ₁ , Jianping Huang ₁ , Genesis D. Renderos ₁ , Calvin D. Quilty ₁ , Alexander B. Brady ₂ , Amy C. Marschilok _{1,

2,

3} , Kenneth J. Takeuchi _{1,

2} , Esther S. Takeuchi _{1,

2,

3}

Affiliation

Future advances in energy storage systems rely on identification of appropriate target materials and deliberate synthesis of the target materials with control of their physiochemical properties in order to disentangle the contributions of distinct properties to the functional electrochemistry. This goal demands systematic inquiry using model materials that provide the opportunity for significant synthetic versatility and control. Ideally, a material family that enables direct manipulation of characteristics including composition, defects, and crystallite size while remaining within the defined structural framework would be necessary. Accomplishing this through direct synthetic methods is desirable to minimize the complicating effects of secondary processing.

中文翻译：

调查α-的MnO ₂隧道式结构作为阳离子型主机的储能

储能系统的未来进展取决于对适当目标材料的识别和目标材料在控制其理化性质的情况下的故意合成，以便弄清不同性质对功能电化学的贡献。这个目标要求使用模型材料进行系统的查询，这些模型材料提供了显着的合成多功能性和控制的机会。理想地，将需要能够直接操纵包括组成，缺陷和微晶尺寸在内的特性，同时保持在定义的结构框架内的材料族。希望通过直接合成的方法来完成这一点，以最小化二次加工的复杂效果。

更新日期：2018-02-19

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