当前位置: X-MOL 学术Gas Sci. Eng. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Are the amino acids thermodynamic inhibitors or kinetic promoters for carbon dioxide hydrates?
Gas Science and Engineering ( IF 5.285 ) Pub Date : 2018-02-19
Pinnelli S.R. Prasad, Burla Sai Kiran

This study deals with the carbon dioxide (CO2) hydrate formation in aqueous solutions, containing 0.5 wt% amino acids (L-valine, L-phenylalanine, L-cysteine, L-methionine and L-threonine) under isochoric conditions. Systematic experiments were conducted in both stirred (300 rpm) and non-stirred configurations. The hydrate formation requires higher sub-cooling than the pure CO2 system. The gas uptake in the hydrates, formed under stirred conditions, in l-val, l-cys and l-met systems is ∼20% higher than the pure system, while in other two (l-phe & l-thr) it is comparable to the pure system. Further, there is no appreciable gas uptake in pure, l-phe and l-thr systems under non-stirred conditions. On the other hand, the gas uptake is higher and faster, similar to stirred conditions, in other three systems, i.e., l-val, l-cys and l-met. Thus, the aqueous solutions consisting of these three amino acids are useful in the CO2 gas capture and storage applications.



中文翻译:

氨基酸是二氧化碳水合物的热力学抑制剂还是动力学促进剂?

这项研究处理的是在等压条件下在水溶液中形成的二氧化碳(CO 2)水合物,其中含有0.5 wt%的氨基酸(L-缬氨酸,L-苯丙氨酸,L-半胱氨酸,L-蛋氨酸和L-苏氨酸)。在搅拌(300 rpm)和非搅拌配置下进行系统性实验。与纯CO 2相比,水合物的形成需要更高的过冷度系统。在l-val,l-cys和l-met系统中,在搅拌条件下形成的水合物中的气体吸收量比纯系统高约20%,而在另两个(l-phe和l-thr)系统中,可与纯系统媲美。此外,在非搅拌条件下,在纯,l-phe和l-thr系统中没有明显的气体吸收。另一方面,类似于搅拌条件,在其他三个系统中,即l-val,l-cys和l-met,气体吸收更高且更快。因此,由这三种氨基酸组成的水溶液可用于CO 2气体捕获和储存应用。

更新日期:2018-02-21
down
wechat
bug