A review on the recent state of spectroelectrochemical techniques is presented. Starting with a discussion of the advantages of the application of spectroelectrochemical techniques instead of an ex-situ combination of spectroscopic and electrochemical methods, the main part of this review is focused on two topics: practical considerations for obtaining the optimal conditions for spectroelectrochemical measurements according to the spectroscopic or electrochemical technique selected, and considerations for the optimal design and construction of spectroelectrochemical cells with examples. The final outlook is intended to the use of spectroelectrochemical detectors in flow injection analysis (FIA) experiments. More than 300 references are collected covering the main contributions on this subject.

提出了对光谱电化学技术的最新状态的审查。首先讨论光谱电化学技术的应用优势，而不是光谱和电化学方法的非原位组合，本综述的主要内容集中在两个主题上：为获得最佳的光谱电化学测量条件而进行的实际考虑。所选的光谱或电化学技术，并结合实例对光谱电化学电池的最佳设计和构造进行了考虑。最终展望旨在在流动注射分析（FIA）实验中使用光谱电化学检测器。收集了300多个参考文献，涵盖了该主题的主要贡献。