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Instilling exploitable INHIBIT logic gate response for F-/H+ in ‘end-off’ anthracene-diamine hybrid by simple functional group manipulation: experimental study aided by DFT calculations
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-02-15 , DOI: 10.1016/j.cplett.2018.02.046
Arghyadeep Bhattacharyya , Subhash Chandra Makhal , Aniruddha Ganguly , Nikhil Guchhait

Two anthracene based receptors ADAMN and ANOPD were synthesized and characterized. The response of both towards F- ion has been monitored by UV-Vis and 1H NMR spectroscopy as well as naked eye color change. Interestingly, change in acceptor unit endows ADAMN to behave as a INHIBIT logic gate with F- and H+ as inputs whereas ANOPD remains totally silent towards F-. The reason for this differential behavior has been explored by DFT calculations. The practical utility of the logic gate response of ADAMN was explored by successful paper strip experiment.



中文翻译:

灌输与F开采INHIBIT逻辑门响应- / H +在“末端断”蒽二胺混合通过简单的官能团操作:通过DFT计算辅助实验研究

合成并表征了两个基于蒽的受体ADAMNANEPD。两者向F上的响应-离子已经通过UV-Vis和监测1 H NMR光谱以及肉眼颜色变化。有趣的是,在受体单元赋予变化ADAMN表现为一个INHIBIT与F逻辑门-和H +作为输入而ANOPD保持完全沉默朝˚F - 。DFT计算已探究了这种差异行为的原因。通过成功的试纸实验,探索了ADAMN逻辑门响应的实用性

更新日期:2018-02-16
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