当前位置: X-MOL 学术J. Chem. Eng. Data › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Comment on “Solid-Liquid Phase Equilibrium and Thermodynamic Properties of Olaparib in Selected Organic Solvents and (Tetrahydrofuran + MTBE, Acetonitrile + Isopropyl Alcohol) Binary Solvent Mixtures”
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2018-02-15 00:00:00 , DOI: 10.1021/acs.jced.7b00955
William E. Acree 1
Affiliation  

Several mathematical errors in the published paper by Zhao and co-workers are identified. The errors pertain to the calculated equation coefficients for the polynomial version of the combined nearly ideal binary solvent (CNIBS)/Redich-Kister and for the Combined Jouyban–Acree–van’t Hoff equation. In the case of the CNIBS/Redlich–Kister equation the authors’ tabulated equation coefficients give 100 times the mole fraction solubility of olaparib, and not the mole fraction solubility as the authors’ equation implies.

中文翻译:

关于“奥拉帕立比在某些有机溶剂和(四氢呋喃+ MTBE,乙腈+异丙醇)二元溶剂混合物中的固相平衡和热力学性质的评论”

Zhao及其同事在发表的论文中发现了一些数学错误。误差与组合的近似理想二元溶剂(CNIBS)/ Redich-Kister的多项式形式和Jouyban-Acree-van't Hoff组合方程的计算方程系数有关。对于CNIBS / Redlich–Kister方程,作者的列表方程系数给出了olaparib的摩尔分数溶解度的100倍,而不是作者方程式所暗示的摩尔分数溶解度。
更新日期:2018-02-16
down
wechat
bug