Porous Organic Polymers via Ring Opening Metathesis Polymerization,ACS Macro Letters

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Porous Organic Polymers via Ring Opening Metathesis Polymerization
ACS Macro Letters ( IF 5.1 ) Pub Date : 2018-02-15 00:00:00 , DOI: 10.1021/acsmacrolett.8b00041
Yanchuan Zhao _{1,

2} , Yuan He ₁ , Timothy M Swager ₁

Affiliation

Highly porous and solution processable organic polymers that can be structurally tailored for various applications are in great demand. Previously reported strategies to prepare porous polymers usually rely on a high level of cross-linking or structurally rigid polymer backbones. We now demonstrate that one-dimensional linear polymers with flexible backbones prepared through ring opening metathesis polymerization can be highly porous. This new strategy allows facile access to diversified porous organic polymers having tunable mechanical/chemical properties bearing different functionalities.

中文翻译：

开环复分解聚合多孔有机聚合物

可以为各种应用在结构上定制的高度多孔和可溶液加工的有机聚合物的需求量很大。先前报道的制备多孔聚合物的策略通常依赖于高水平的交联或结构刚性的聚合物骨架。我们现在证明通过开环复分解聚合制备的具有柔性主链的一维线性聚合物可以是高度多孔的。这种新策略允许轻松获得多样化的多孔有机聚合物，这些聚合物具有可调节的机械/化学性质，具有不同的功能。

更新日期：2018-02-15

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