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Electrochemical synthesis of methyl sulfoxides from thiophenols/thiols and dimethyl sulfoxide
Green Chemistry ( IF 9.3 ) Pub Date : 2018-02-15 00:00:00 , DOI: 10.1039/c7gc03864j
Ke-Si Du 1, 2, 3, 4, 5 , Jing-Mei Huang 1, 2, 3, 4, 5
Affiliation  

A new route for a one-pot synthesis of methyl sulfoxides from thiophenols/thiols and dimethyl sulfoxide using an electrochemical technique was developed. This protocol proceeded smoothly by employing electrons and hydrogen peroxide as clean oxidants, and a wide range of aromatic and aliphatic sulfoxides were synthesized in moderate to good yields.

中文翻译:

由硫酚/硫醇和二甲基亚砜电化学合成甲基亚砜

开发了一种使用电化学技术从苯酚/硫醇和二甲基亚砜一锅法合成甲基亚砜的新途径。该方案通过使用电子和过氧化氢作为清洁氧化剂而顺利进行,并以中等至良好的产率合成了多种芳族和脂族亚砜。
更新日期:2018-03-20
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