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Direct transesterification of black soldier fly larvae (Hermetia illucens) for biodiesel production
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.5 ) Pub Date : 2018-02-14 , DOI: 10.1016/j.jtice.2018.01.035
Hoang Chinh Nguyen , Shih-Hsiang Liang , Sing-Ying Li , Chia-Hung Su , Chien-Chung Chien , Yi-Ju Chen , Dinh Thi My Huong

In this study, direct transesterification with a combination of methanol and a cosolvent was demonstrated to be promising for the production of biodiesel from black soldier fly larvae (BSFL) biomass. Of the solvents tested, n-hexane was identified as the most effective cosolvent for the reaction, resulting in a 14.5-fold increase in the biodiesel yield, compared with the reaction without a cosolvent. The direct transesterification using n-hexane as a cosolvent was then optimized to maximize the biodiesel yield. The highest biodiesel yield of 94.14% was achieved at an n-hexane:methanol volume ratio of 1:2 (v/v), a solvent dosage of 12 mL, a catalyst loading of 1.2 mL, a temperature of 120°C, and a reaction time of 90 min. The properties of the BSFL biodiesel were also tested, and most—such as the biodiesel's density (875 kg/m3), water content (0.03 mg/kg), ester content (98.3%), acid value (<0.8 mg KOH/g), viscosity (5.2 mm2/s), flash point (121°C), and cetane index (50)—met the specifications of the European standard EN 14214. This study suggested that direct transesterification using n-hexane as a cosolvent could be a promising method for biodiesel production from BSFL and decrease production costs.



中文翻译:

黑色士兵蝇蝇幼虫(Hermetia illucens)直接酯交换用于生产生物柴油

在这项研究中,甲醇与助溶剂的直接酯交换反应被证明对从黑士兵蝇幼虫(BSFL)生物量生产生物柴油很有希望。在测试的溶剂中,正己烷被确定为该反应最有效的助溶剂,与没有助溶剂的反应相比,生物柴油收率提高了14.5倍。然后优化使用正己烷作为助溶剂的直接酯交换反应,以最大程度地提高生物柴油的收率。在正己烷:甲醇体积比为1:2(v / v),溶剂剂量为12 mL,催化剂负载为1.2 mL,温度为120的条件下,获得最高的生物柴油收率94.14%,反应时间为90分钟。还测试了BSFL生物柴油的特性,以及大多数-例如生物柴油的密度(875 kg / m 3),水含量(0.03 mg / kg),酯含量(98.3%),酸值(<0.8 mg KOH / g),粘度(5.2 mm 2 / s),闪点(121°C)和十六烷指数(50)-符合欧洲标准EN 14214的规范。这项研究表明,使用正己烷作为助溶剂的直接酯交换反应可能是从BSFL生产生物柴油并降低生产成本的一种有前途的方法。

更新日期:2018-02-14
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