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Olefination with Sulfonyl Halides and Esters: E‐Selective Synthesis of Alkenes from Semistabilized Carbanion Precursors
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-04-19 , DOI: 10.1002/ejoc.201701766
Bartosz Górski 1 , Dariusz Basiak 1, 2 , Alicja Talko 1 , Tymoteusz Basak 1 , Tomasz Mazurek 1, 2 , Michał Barbasiewicz 1
Affiliation  

Sulfur‐based olefination with Horner–Wadsworth–Emmons‐type mechanism is systematically studied. Nonstabilized and semistabilized carbanion precursors react with carbonyl compounds giving good yields of olefins, and for the latter reagents E isomers of alkenes predominate.
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中文翻译:

磺酰卤和酯的烯烃化:从半稳定的碳负离子前体的电子选择性合成烯烃。

系统地研究了基于霍纳-沃兹沃思-埃蒙斯型机理的硫基烯烃化反应。未稳定的和半稳定的碳负离子前体与羰基化合物反应,可提供良好的烯烃收率,而对于后一种试剂,烯烃的E异构体占主导地位。
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更新日期:2018-04-19
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