当前位置: X-MOL 学术Eur. J. Org. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Addition of Organozinc Reagents to Glycopyranosyl Cyanides: Access to Keto Ester‐C‐glycosides or Unsaturated Acyl‐C‐glycosides
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-04-17 , DOI: 10.1002/ejoc.201800090
Idriss Ella Obame 1 , Prathap Ireddy 1 , Nicolas E. S. Guisot 1 , Arnaud Nourry 1 , Christine Saluzzo 1 , Gilles Dujardin 1 , Didier Dubreuil 2 , Muriel Pipelier 2 , Stéphane Guillarme 1
Affiliation  

Original keto ester‐C‐glycosides or unsaturated acyl‐C‐glycosides have been prepared in moderate to excellent yields in the galactose, glucose and mannose series by reactions involving addition of Reformatsky‐type or allylic zinc reagents to 2,3,4,6‐tetra‐O‐benzylglycopyranosyl cyanides.
image


中文翻译:

在Glycopyranosyl氰化物中添加有机锌试剂:获得Keto Ester-C-glycosides或不饱和的Acyl-C-glycosides

通过将Reformatsky型或烯丙基锌试剂添加到2,3,4,6中的反应,已在半乳糖,葡萄糖和甘露糖系列中以中等至极高的收率制备了原始的酮酯C-糖苷或不饱和酰基C-糖苷。 -四-O-苄基甘露糖基氰化物。
图像
更新日期:2018-04-17
down
wechat
bug