Metal–Organic Frameworks as Platform Materials for Solar Fuels Catalysis,ACS Energy Letters

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Metal–Organic Frameworks as Platform Materials for Solar Fuels Catalysis
ACS Energy Letters ( IF 19.3 ) Pub Date : 2018-02-12 00:00:00 , DOI: 10.1021/acsenergylett.8b00010
Marek B. Majewski ₁ , Aaron W. Peters _{1,

2} , Michael R. Wasielewski _{1,

2} , Joseph T. Hupp _{1,

2} , Omar K. Farha _{1,

2,

3}

Affiliation

Metal–organic frameworks (MOFs) are promising platform materials for solar fuels catalysis owing, in part, to their synthetic tunability and variability. MOFs can be designed and employed as supports for known molecular and nanoparticulate catalysts and for new atomically precise cluster-based catalysts. Rational modification of the organic linkers that define the framework affords the possibility of incorporating known photosensitizers or functional groups to generate hybrid materials that can serve to absorb light, facilitate substrate transport, and catalyze chemical reactions. In this Review, we highlight the diversity of approaches that have been taken to functionalizing, designing, and modifying MOFs for solar fuels generation where MOFs have typically been used as supports or as scaffolds for known catalysts. We additionally highlight the potential of MOFs as platform materials for new and existing cluster-based heterogeneous catalytic systems where both the active sites and the support can be characterized with near atomic-scale precision.

中文翻译：

金属有机框架作为太阳能燃料催化的平台材料

金属有机框架（MOF）是有前途的太阳能燃料催化平台材料，部分原因是其合成的可调性和可变性。可以设计MOF并将其用作已知分子和纳米颗粒催化剂以及新的原子精确的基于簇的催化剂的载体。限定框架的有机连接基的合理修饰提供了掺入已知的光敏剂或官能团以产生杂化材料的可能性，所述杂化材料可用于吸收光，促进底物运输和催化化学反应。在本综述中，我们重点介绍了功能化，设计和修改用于太阳能发电的MOF的方法的多样性，其中MOF通常用作已知催化剂的载体或支架。

更新日期：2018-02-12

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