Highly-functionalized arene synthesis based on palladium on carbon-catalyzed aqueous dehydrogenation of cyclohexadienes and cyclohexenes,Green Chemistry

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Highly-functionalized arene synthesis based on palladium on carbon-catalyzed aqueous dehydrogenation of cyclohexadienes and cyclohexenes
Green Chemistry ( IF 9.3 ) Pub Date : 2018-02-09 00:00:00 , DOI: 10.1039/c7gc03819d
Naoki Yasukawa _{1,

2,

3,

4} , Hiroki Yokoyama _{1,

2,

3,

4} , Masahiro Masuda _{1,

2,

3,

4} , Yasunari Monguchi _{1,

2,

3,

4} , Hironao Sajiki _{1,

2,

3,

4} , Yoshinari Sawama _{1,

2,

3,

4}

Affiliation

Transition metal-catalyzed dehydrogenation is a clean oxidation method requiring no additional oxidants. We have accomplished a heterogeneous Pd/C-catalyzed aqueous dehydrogenation of 1,4-cyclohexadienes and cyclohexenes to give the corresponding highly-functionalized arenes. Furthermore, various arenes could be efficiently constructed in a one-pot manner via a Diels–Alder reaction and the following dehydrogenation.

中文翻译：

碳催化环己二烯和环己烯的水脱氢基于钯的高官能度芳烃合成

过渡金属催化的脱氢是一种清洁的氧化方法，不需要其他氧化剂。我们已经完成了Pd / C催化的1,4-环己二烯和环己烯的异水脱氢反应，得到了相应的高度官能化的芳烃。此外，可以通过Diels-Alder反应和随后的脱氢反应以一锅法高效地构建各种芳烃。

更新日期：2018-03-20

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