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Growth of SnO2 Nanoflowers on N-doped Carbon Nanofibers as Anode for Li- and Na-ion Batteries
Nano-Micro Letters ( IF 31.6 ) Pub Date : 2017-12-08 , DOI: 10.1007/s40820-017-0172-2
Jiaojiao Liang , Chaochun Yuan , Huanhuan Li , Kai Fan , Zengxi Wei , Hanqi Sun , Jianmin Ma

It is urgent to solve the problems of the dramatic volume expansion and pulverization of SnO2 anodes during cycling process in battery systems. To address this issue, we design a hybrid structure of N-doped carbon fibers@SnO2 nanoflowers (NC@SnO2) to overcome it in this work. The hybrid NC@SnO2 is synthesized through the hydrothermal growth of SnO2 nanoflowers on the surface of N-doped carbon fibers obtained by electrospinning. The NC is introduced not only to provide a support framework in guiding the growth of the SnO2 nanoflowers and prevent the flower-like structures from agglomeration, but also serve as a conductive network to accelerate electronic transmission along one-dimensional structure effectively. When the hybrid NC@SnO2 was served as anode, it exhibits a high discharge capacity of 750 mAh g−1 at 1 A g−1 after 100 cycles in Li-ion battery and 270 mAh g−1 at 100 mA g−1 for 100 cycles in Na-ion battery, respectively.
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中文翻译:

SnO的生长2个 N掺杂碳纳米纤维上的纳米花作为锂离子和钠离子电池的阳极

解决电池系统循环过程中SnO 2阳极体积急剧膨胀和粉化的问题迫在眉睫。为了解决这个问题,我们设计了一种N掺杂碳纤维@SnO 2纳米花(NC @ SnO 2)的混合结构来克服这一问题。杂化NC @ SnO 2是通过在电纺丝得到的N掺杂碳纤维表面上水热生长SnO 2纳米花而合成的。引入NC不仅为指导SnO 2的生长提供了支持框架。纳米花,可以防止花状结构的团聚,而且还可以作为导电网络有效地促进电子沿着一维结构的传输。当将杂化NC @ SnO 2用作阳极时,它在锂离子电池中循环100次后在1 A g -1下表现出750 mAh g -1的高放电容量,而在100 mA g -1下表现出270 mAh g -1的高放电容量。在Na离子电池中分别可循环100次。
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更新日期:2017-12-08
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