当前位置: X-MOL 学术Eur. J. Org. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Thermal Ring Expansion of 2‐Sulfonylimidoyl‐1‐phthalimidoaziridines into N‐Sulfonylimidazoles
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-04-14 , DOI: 10.1002/ejoc.201701806
Aleksandr Stukalov 1 , Vitalii V. Suslonov 2 , Mikhail A. Kuznetsov 1
Affiliation  

Di‐, tri‐substituted, and spiro‐fused 2‐sulfonylimidoyl‐1‐phthalimidoaziridines are transformed to di‐, tri‐substituted, and condensed N‐sulfonylimidazoles upon thermolysis. This ring expansion is accompanied by an intramolecular 1,3‐sulfonyl shift.
image


中文翻译:

2-磺酰氨基亚胺基-1-邻苯二甲酰亚胺基氮杂环丁烷的热环扩展成N-磺酰氨基咪唑

在热解后,二,三取代和螺旋稠合的2-磺酰亚胺基1-1-邻苯二甲酰亚胺基氮杂环丁烷转化为二,三取代和缩合的N-磺酰亚胺基咪唑。这种环的扩张伴随着分子内的1,3-磺酰基转移。
图像
更新日期:2018-04-14
down
wechat
bug