Catalysis Communications ( IF 3.4 ) Pub Date : 2018-02-07 , DOI: 10.1016/j.catcom.2018.02.006 Zhiqiang Chen , Pingxing Xing , Pengfei Chen , Qianqian Chen , Yan Wang , Jingxiong Yu , Yiming He
Carbon-doped KTaO3 was synthesized for the first time via a simple combination of hydrothermal and calcination processes with glucose as the carbon source. XRD and XPS characterizations proved the successful introduction of the carbon atoms into the KTaO3 lattice. Photocatalytic test showed that the carbon-doped KTaO3 presented excellent performance in photocatalytic H2 generation under simulated sunlight illumination, mainly due to the enhanced separation of electron-hole pairs. The optimal sample presents a H2 generation rate of 592 μmol g−1 h−1, which reaches 2.6 times that of pure KTaO3.
中文翻译:
碳掺杂KTaO 3的合成及其在光催化H 2生成中的增强性能
通过将葡萄糖作为碳源的水热和煅烧工艺的简单组合,首次合成了掺碳的KTaO 3。XRD和XPS表征证明了将碳原子成功引入KTaO 3晶格中。光催化试验表明,掺杂碳的KTaO 3在模拟的阳光照射下表现出优异的光催化H 2生成性能,这主要是由于电子-空穴对的分离增强了。最佳样品的H 2生成速率为592μmolg -1 h -1,是纯KTaO 3的2.6倍。