Synthesis of α‐Fluorinated Acrylates by a Palladium‐Catalyzed Decarboxylative Olefination Reaction,European Journal of Organic Chemistry

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Synthesis of α‐Fluorinated Acrylates by a Palladium‐Catalyzed Decarboxylative Olefination Reaction
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-02-07 , DOI: 10.1002/ejoc.201701709
Ouafa Bouazzaoui _{1,

2} , Kevin Rousée ₁ , Joseph Kajima Mulengi ₂ , Xavier Pannecoucke ₁ , Jean-Philippe Bouillon ₁ , Samuel Couve-Bonnaire ₁

Affiliation

Ligand‐free palladium‐catalyzed subsequent decarboxylation/olefination reaction between 2‐fluorinated acrylates and benzoic acids is reported. Valuable trisubstituted 2‐fluoroacrylates and 2‐trifluoromethylacrylates were produced in low to excellent yields, which constitutes a new interesting greener synthetic alternative to these fluorinated molecules.

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