AbstractThis review demonstrates our approaches for developing functional polymer systems using dissociation processes in nonpolar media. One is the molecular design of highly swellable gels known as superabsorbent polymers in nonpolar organic solvents, and the other is the supramolecular design of thermo-responsive polymers. Both of them are well documented in water, but no practical molecular design for other media have ever been proposed. For designing these behaviors, the dissociation or release of the low-molecular component from macromolecular complexes should play a key role. Therefore, controlling the dissociation processes in supramolecular chemistry should be another important strategy for developing functional polymer materials.This review focuses on our novel approaches for developing functional polymers by dissociation phenomena of macromolecular complexes. One is highly swellable polymer gels, superabsorbent polymers for nonpolar organic solvents, and the other is thermo-responsive polymers at ambient temperature in nonpolar solvents. Both of them are well-known in water, but no design has ever been proposed for other media. The dissociation of the macromolecular complexes plays a key role for them. Therefore, controlling the dissociation processes in supramolecular chemistry should be another important strategy for emerged dynamic functions.

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大分子复合物解离诱导的非极性溶剂中的功能聚合物

摘要这篇综述展示了我们在非极性介质中使用解离过程开发功能性聚合物系统的方法。一种是在非极性有机溶剂中被称为高吸水性聚合物的高度溶胀凝胶的分子设计，另一种是热响应聚合物的超分子设计。它们都在水中得到了很好的记录，但尚未提出其他介质的实用分子设计。为了设计这些行为，大分子复合物中低分子组分的解离或释放应该发挥关键作用。因此，控制超分子化学中的解离过程应该是开发功能性高分子材料的另一个重要策略。本综述侧重于我们通过大分子复合物的解离现象开发功能聚合物的新方法。一种是高度可溶胀的聚合物凝胶，用于非极性有机溶剂的超吸收聚合物，另一种是环境温度下在非极性溶剂中的热响应聚合物。它们都在水中广为人知，但从未针对其他媒体提出过设计。大分子复合物的解离对它们起着关键作用。因此，控制超分子化学中的解离过程应该是出现动态函数的另一个重要策略。它们都在水中广为人知，但从未针对其他媒体提出过设计。大分子复合物的解离对它们起着关键作用。因此，控制超分子化学中的解离过程应该是出现动态函数的另一个重要策略。它们都在水中广为人知，但从未针对其他媒体提出过设计。大分子复合物的解离对它们起着关键作用。因此，控制超分子化学中的解离过程应该是出现动态函数的另一个重要策略。