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Recyclable heat-resisting polymer poly(ether azaindole ketone)-H+via hydrogen bonding crosslinking†
Polymer Chemistry ( IF 4.1 ) Pub Date : 2018-02-07 00:00:00 , DOI: 10.1039/c7py02097j
Q. Yin 1, 2, 3, 4 , Y. Peng 1, 2, 3, 4 , S. Zhang 1, 2, 3, 4 , F. Zhu 1, 2, 3, 4 , W. Li 1, 2, 3, 4 , K. Du 1, 2, 3, 4
Affiliation  

Chemically crosslinked heat-resisting polymers have many industrial applications, but are difficult to recycle or rework. We prepared a novel recyclable hydrogen bonding crosslinked polymer PEAINKH+, which possesses outstanding thermal stability including high Tg (246 °C) and Td (489 °C). And the hydrogen bonding interactions can be further removed via external alkali to recover the linear polymer PEAINK, which endows the crosslinking polymer with a recyclable behavior.

中文翻译:

可回收耐热聚合物的聚(醚酮氮杂吲哚)-H +经由氢键交联

化学交联的耐热聚合物具有许多工业应用,但是难以回收或再加工。我们制备了一种新型的可回收氢键交联聚合物PEAINKH +,它具有出色的热稳定性,包括高T g(246°C)和T d(489°C)。氢键相互作用可以通过外部碱进一步除去以回收线性聚合物PEAINK,从而使交联聚合物具有可回收的行为。
更新日期:2018-02-07
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