Over the past few decades, two-dimensional graphene based materials (2DGMs) have piqued the interest of scientists worldwide, and the exploration of their potential applications in catalysis, sensors, electronic devices and energy storage due to their extraordinary physical and chemical properties has rapidly progressed. As for these 2DGMs, there is a complementary need to assemble 2D building blocks hierarchically into more complicated and hierarchical three-dimensional graphene-based materials (3DGMs). Such a capability is vitally crucial in order to design sophisticated and multi-functional catalysts with tailorable properties. This comprehensive review describes some important recent advances with respect to 3DGMs, including their preparation methods, characterization and applications in catalysis, e.g., photocatalysis, electrocatalysis, organic catalysis, and CO oxidation. The importance of the relationship between the structure and catalytic performance, a topic which has become a central focus of research in order to develop high-performance catalytic systems, is discussed. Likely future developments and their associated challenges are proposed and discussed.

中文翻译：

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三维石墨烯基材料在催化领域的最新进展

在过去的几十年中，二维石墨烯基材料（2DGM）引起了全世界科学家的兴趣，由于其非凡的物理和化学性质，对它们在催化，传感器，电子设备和能量存储中的潜在应用的探索已迅速开展。进步了。对于这些2DGM，有一种补充需求，即将2D构建基块分层地组装到更复杂和层次化的基于三维石墨烯的材料（3DGM）中。为了设计具有可定制性能的复杂和多功能催化剂，这种能力至关重要。这份全面的综述描述了有关3DGM的一些重要的最新进展，包括其制备方法，表征和在催化中的应用，例如，光催化，电催化，有机催化和CO氧化。讨论了结构与催化性能之间关系的重要性，该主题已成为开发高性能催化系统的研究重点。提出并讨论了未来的发展及其可能带来的挑战。