This review is devoted to porphyrin-based film materials. Various technological and scientific applications of ones are close to surface and interface related phenomena. In the part I of review the following topics are discussed the recent progress in field of submonolayers, monolayers and multilayers films on the vapor-solid interfaces, including results on (i) conformational behavior of adsorbed molecules, (ii) aggregation and surface phases formation, (iii) on-surface coordination networks, and (iv) on-surface chemical reactions. The examples of combined approaches to developing materials and porphyrin-based film materials application are also presented.

中文翻译：

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卟啉基薄膜材料的结构和性能第I部分：通过蒸气辅助法获得的薄膜

这篇评论专门针对基于卟啉的薄膜材料。它们的各种技术和科学应用都接近与表面和界面相关的现象。在综述的第一部分中，以下主题讨论了气固界面上亚单层，单层和多层薄膜领域的最新进展，包括以下方面的结果：（i）吸附分子的构象行为，（ii）聚集和表面相形成，（iii）表面协调网络和（iv）表面化学反应。还介绍了开发材料和基于卟啉的薄膜材料的组合方法的示例。