当前位置: X-MOL 学术Chem. Phys. Lett. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Determination of molar enthalpy of sublimation in case of orotic acid as obtained from experimental and computational data
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-02-06 , DOI: 10.1016/j.cplett.2018.02.008
Ilya I. Marochkin , Ekaterina P. Altova , Norbert S. Chilingarov , Anna L. Vilkova , Igor F. Shishkov

Saturated vapor pressure, ln(p/Pa)=(-21316±511)/(T /K)+(41.64±0.11), and enthalpy of sublimation of orotic acid, ΔsubHm0(Tm) = 177 ± 4 kJ/mol, were determined by means of Knudsen effusion mass spectrometry in the temperature range of 423÷493 K. The computational approaches supported the experimental results reported. The theoretical estimation of the gas-phase enthalpy of formation for orotic acid was done with different working reactions used.



中文翻译:

从实验和计算数据确定在乳清酸情况下升华的摩尔焓焓

饱和蒸气压ln(p / Pa)=(-21316±511)/(T / K)+ ( 41.64 ± 0.11)和乳清酸的升华焓,ΔH0Ť在423÷493 K的温度范围内,通过Knudsen渗流质谱法确定了177±4 kJ / mol。计算方法支持了所报道的实验结果。对乳清酸的气相生成焓的理论估算是通过使用不同的反应进行的。

更新日期:2018-02-07
down
wechat
bug