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Fluorine‐Containing Functionalized Cyclopentene Scaffolds Through Ring Contraction and Deoxofluorination of Various Substituted Cyclohexenes
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-02-06 , DOI: 10.1002/ejoc.201800057
Attila Márió Remete 1 , Melinda Nonn 2 , Santos Fustero 3 , Matti Haukka 4 , Ferenc Fülöp 1, 2 , Loránd Kiss 1
Affiliation  

The fluorination of some highly‐functionalized cyclopentene derivatives, obtained from various substituted cyclohexenes through a ring‐opening/ring‐contraction procedure, has been investigated. The transformations were found to be highly substrate dependent, and led to the formation of various functionalized alicyclic compounds or heterocycles containing allyl difluoride or vinyl fluoride moieties.

中文翻译:

通过各种取代的环己烯的环收缩和脱氧氟化作用,实现含氟功能化环戊烯骨架的制备。

已经研究了通过开环/缩环程序从各种取代的环己烯中获得的一些高度官能化的环戊烯衍生物的氟化反应。发现该转化高度依赖于底物,并导致形成各种官能化的脂环族化合物或含有二氟烯丙基或氟乙烯部分的杂环。
更新日期:2018-06-03
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