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Transparent Sr0.84Lu0.16F2.16: Yb3+, Er3+ glass ceramics: Elaboration, structure, up-conversion properties and applications
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2018-02-06 , DOI: 10.1016/j.jeurceramsoc.2018.02.010
Jiangkun Cao , Dengke Xu , Fangfang Hu , Xiaoman Li , Weiping Chen , LiPing Chen , Hai Guo

The development of optical temperature sensors is of fundamental and industrial importance for various applications. Despite the great advance in optical temperature-sensing techniques, challenges remain to search for novel sensing materials with low cost, easy fabrication and high sensitivity. Here, transparent glass ceramics (GC) embedded with cubic Sr0.84Lu0.16F2.16:Yb3+/Er3+ nano-crystals were prepared via thermal annealing on the parent glass. The optical and structural properties were investigated. The enhanced emission intensity, obvious Stark splitting and prolonged lifetimes of Er3+ confirm the enrichment of Er3+ ions into formed Sr0.84Lu0.16F2.16 nano-crystals. The temperature sensing performance of Yb3+/Er3+ ions in Sr0.84Lu0.16F2.16GC were investigated based on up-conversion intensity ratio (FIR) from thermally coupled emitting states of Er3+. High energy difference (ΔE = 839 cm−1) and high absolute sensitivity (27.4 × 10−4 K−1 at 606 K) are obtained. Our results reveal Sr0.84Lu0.16F2.16GC are excellent host for rare earth ions doping and potential candidate for optical thermometry.



中文翻译:

透明Sr 0.84 Lu 0.16 F 2.16:Yb 3+,Er 3+玻璃陶瓷:结构,上转换特性和应用

光学温度传感器的发展对于各种应用具有根本和工业重要性。尽管光学温度传感技术取得了巨大进步,但寻找低成本,易于制造和高灵敏度的新型传感材料仍然面临挑战。在此,通过在母玻璃上进行热退火来制备嵌入有立方Sr 0.84 Lu 0.16 F 2.16:Yb 3+ / Er 3+纳米晶体的透明玻璃陶瓷(GC)。研究了光学和结构性质。增强的发射强度,明显的Stark分裂和Er 3+的寿命延长证明了Er 3+离子富集到形成的Sr中0.84 Lu 0.16 F 2.16纳米晶体。基于Er 3+的热耦合发射态的上转换强度比(FIR),研究了Sr 0.84 Lu 0.16 F 2.16 GC中Yb 3+ / Er 3+离子的温度传感性能。高能量差(ΔE = 839 cm -1)并获得高绝对灵敏度(606 K时为27.4×10 -4  K -1)。我们的结果表明,Sr 0.84 Lu 0.16 F 2.16 GC是稀土离子掺杂的极好宿主,并且是光学测温的潜在候选者。

更新日期:2018-02-06
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