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MoS2 Quantum Dots‐Modified Covalent Triazine‐Based Frameworks for Enhanced Photocatalytic Hydrogen Evolution
ChemSusChem ( IF 8.4 ) Pub Date : 2018-02-23 , DOI: 10.1002/cssc.201702220
Qianqian Jiang 1 , Long Sun 1 , Jinhong Bi 1, 2 , Shijing Liang 1, 2 , Liuyi Li 3 , Yan Yu 3 , Ling Wu 2
Affiliation  

MoS2 quantum dots (QDs)‐modified covalent triazine‐based framework (MoS2/CTF) composites are synthesized through an in situ photodeposition method. MoS2 QDs are well distributed and stabilized on the layers of CTFs by coordination of the frameworks to MoS2. The QDs–sheet interactions between MoS2 and CTFs facilitate interfacial charge transfer and separation. As a consequence, the composites exhibit outstanding photocatalytic activity and stability for hydrogen evolution under visible light irradiation (λ≥420 nm), that exceed those over pristine CTFs and MoS2‐modified g‐C3N4 (MoS2/g‐C3N4) composite, making them promising materials for solar energy conversion.

中文翻译:

MoS2量子点修饰的基于共价三嗪的骨架,可增强光催化氢的逸出

MoS 2量子点(QDs)改性的基于共价三嗪的骨架(MoS 2 / CTF)复合材料是通过原位光沉积法合成的。的MoS 2的QD中良好分布和由所述框架的协调稳定在CTFS的各层的MoS 2。MoS 2和CTF之间的QDs-sheet相互作用促进了界面电荷的转移和分离。其结果是,复合材料表现出出色的光催化活性和对可见光照射(下析氢稳定性λ ≥420nm)时,超过那些超过原始CTFS和MoS 2 -改性-C 3 Ñ 4(MOS2 / g- C 3 N 4)复合材料,使其成为太阳能转化的有前途的材料。
更新日期:2018-02-23
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