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A simple model for constant storage modulus of poly (lactic acid)/poly (ethylene oxide)/carbon nanotubes nanocomposites at low frequencies assuming the properties of interphase regions and networks
Journal of the Mechanical Behavior of Biomedical Materials ( IF 3.3 ) Pub Date : 2018-02-02 , DOI: 10.1016/j.jmbbm.2018.01.037
Yasser Zare , Sungsoo Rhim , Hamid Garmabi , Kyong Yop Rhee

The networks of nanoparticles in nanocomposites cause solid-like behavior demonstrating a constant storage modulus at low frequencies. This study examines the storage modulus of poly (lactic acid)/poly (ethylene oxide)/carbon nanotubes (CNT) nanocomposites. The experimental data of the storage modulus in the plateau regions are obtained by a frequency sweep test. In addition, a simple model is developed to predict the constant storage modulus assuming the properties of the interphase regions and the CNT networks. The model calculations are compared with the experimental results, and the parametric analyses are applied to validate the predictability of the developed model. The calculations properly agree with the experimental data at all polymer and CNT concentrations. Moreover, all parameters acceptably modulate the constant storage modulus. The percentage of the networked CNT, the modulus of networks, and the thickness and modulus of the interphase regions directly govern the storage modulus of nanocomposites. The outputs reveal the important roles of the interphase properties in the storage modulus.



中文翻译:

假设相间区域和网络的特性,聚乳酸/聚环氧乙烷/碳纳米管纳米复合材料在低频下恒定储能模量的简单模型

纳米复合材料中的纳米颗粒网络会产生类似固体的行为,表明在低频下具有恒定的储能模量。这项研究检查了聚(乳酸)/聚(环氧乙烷)/碳纳米管(CNT)纳米复合材料的储能模量。高原区域的储能模量的实验数据通过扫频测试获得。另外,假设相间区域和CNT网络的性质,开发了一个简单的模型来预测恒定的储能模量。将模型计算与实验结果进行比较,并应用参数分析来验证所开发模型的可预测性。该计算与所有聚合物和CNT浓度下的实验数据完全吻合。而且,所有参数均可接受地调节恒定储能模量。网络化的CNT的百分比,网络的模量以及相间区域的厚度和模量直接控制着纳米复合材料的储能模量。输出揭示了相变性质在储能模量中的重要作用。

更新日期:2018-02-02
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