gem-Difluorinated phosphonium salts, generated from aldehydes and difluorinated phosphobetaine reagent, were converted into corresponding silicon reagents. The reductive silylation of carbon-phosphorus bond is carried out using a combination of magnesium and chlorotrimethylsilane in dimethylformamide. For a model difluoroined phosphonium salt, X-ray structure and reduction potential are provided.

中文翻译：

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宝石-二氟化phospho盐的还原甲硅烷基化

宝石-Difluorinated鏻盐，从醛和二氟化磷酸酯试剂产生的，被转换成相应的硅试剂。碳-磷键的还原甲硅烷基化是通过在二甲基甲酰胺中使用镁和氯代三甲基硅烷的组合来进行的。对于模型二氟代phospho盐，提供了X射线结构和还原电位。