The use of host-guest interactions to direct the controllable self-assembly of inorganic nanoparticles has aroused intensive interest in recent years. Through deliberate surface modifications of inorganic nanoparticles, the recognition between host and guest molecules drives the dynamic self-assembly of nanoparticles, leading to fascinating assembly behaviors such as stimulus-responsive and reversible self-assembly. In this review, we first briefly introduce the structures and properties of the typical host molecules, such as cyclodextrins, cucurbit[n]urils, calix[n]arenes, and pilla[n]arenas, and their supramolecular complexes with guest molecules, which have been frequently employed in nanoparticle assembly. Then, recent advances in the approaches toward precise control over the dynamic self-assembly processes of inorganic nanoparticles based on rational regulation of host-guest interactions are summarized with special emphasis on the assembly strategies. Furthermore, the potential applications of the self-assembly systems involving host-guest interactions in sensing and catalysis are highlighted. An outlook on future developments in this field is also provided.

近年来，使用主体-客体相互作用来指导无机纳米颗粒的可控自组装引起了人们的浓厚兴趣。通过对无机纳米粒子进行有意的表面修饰，主体分子和客体分子之间的识别将驱动纳米粒子的动态自组装，从而导致令人着迷的组装行为，例如刺激响应和可逆的自组装。在这篇综述中，我们首先简要介绍典型宿主分子的结构和特性，例如环糊精，葫芦[ n ] urils，杯[ n ]芳烃和pilla [ n]。] arenas及其与客体分子的超分子复合物，它们经常被用于纳米粒子组装中。然后，总结了基于对宿主-客体相互作用的合理调节而精确控制无机纳米粒子动态自组装过程的方法的最新进展，其中特别强调了组装策略。此外，强调了涉及宿主-客体相互作用的自组装系统在传感和催化中的潜在应用。还提供了对该领域未来发展的展望。