Amino acid-derived stimuli-responsive polymers and their applications,Polymer Chemistry

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Amino acid-derived stimuli-responsive polymers and their applications
Polymer Chemistry ( IF 4.1 ) Pub Date : 2018-01-30 00:00:00 , DOI: 10.1039/c7py02014g
Kamal Bauri _{1,

2,

3} , Mridula Nandi _{3,

4,

5,

6} , Priyadarsi De _{3,

4,

5,

6}

Affiliation

Natural biopolymers such as proteins and nucleic acids in living organisms possess an inherent ability to respond to local environmental stimuli, which motivated researchers to make biomolecule-derived non-biological macromolecules with a biomimetic structure having stimuli-responsive properties. This review mainly focuses on stimuli-responsive polymers having natural amino acid units either in the main-chain or in the side-chain, their self-assembled nanostructures and hydrogel networks. Recent advances in the design and synthesis of amino acid-derived polymers that are responsive to various physical, chemical, or biochemical stimuli such as temperature, light, pH, redox-, metal ions, gas, glucose, enzyme, proteins, DNA or a combination of these are illustrated. Their potential for use as stimuli-responsive “smart” nanomaterials in biomedical and biotechnological applications such as in controlled drug delivery, gene delivery, non-fouling materials, etc. is also highlighted. The primary aim of this review article is to motivate researchers towards the design and synthesis of novel stimuli-responsive biohybrid materials for making next generation smart materials.

中文翻译：

氨基酸来源的刺激响应聚合物及其应用

活生物体中的天然生物聚合物（例如蛋白质和核酸）具有对局部环境刺激做出反应的固有能力，这促使研究人员制造出具有仿生结构且具有刺激响应特性的生物分子衍生的非生物大分子。这篇综述主要集中于在主链或侧链中具有天然氨基酸单元的刺激响应性聚合物，它们的自组装纳米结构和水凝胶网络。对各种物理，化学或生物化学刺激（例如温度，光，pH，氧化还原，金属离子，气体，葡萄糖，酶，蛋白质，DNA或DNA）的响应的氨基酸衍生聚合物的设计和合成方面的最新进展。说明了这些的组合。等。也突出显示。这篇综述文章的主要目的是激励研究人员设计和合成新颖的刺激性生物杂交材料，以制造下一代智能材料。

更新日期：2018-01-30

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