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Toward High-Safety Potassium–Sulfur Batteries Using a Potassium Polysulfide Catholyte and Metal-Free Anode
ACS Energy Letters ( IF 22.0 ) Pub Date : 2018-01-29 00:00:00 , DOI: 10.1021/acsenergylett.8b00037
Jang-Yeon Hwang , Hee Min Kim , Chong S. Yoon , Yang-Kook Sun

Based on the reversible conversion reactions, K2Sx (5 ≤ x ≤ 6) K2S3 K2S5, the proposed K–S battery delivered a high discharge capacity of ∼400 mAh g–1 at 0.1 C-rate with stable cycle retention (94% after 20 cycles) and good rate capability up to 2 C-rate. In addition, instead of an explosive and highly reactive potassium metal electrode, a full cell consisting of an electrochemically potassium-impregnated hard carbon and the K2Sx (5 ≤ x ≤ 6) catholyte was constructed to demonstrate the feasibility of a safe K–S battery system free of metallic potassium.

中文翻译:

使用多硫化钾正极液和无金属阳极的高安全性钾硫电池

基于该可逆转化反应,K 2小号X(5≤ X ≤6)ķ 2小号3 ķ 2小号5,所提出的K-硫电池递送的〜400毫安g的高放电容量-1以0.1C速率具有稳定的循环保持能力(20个循环后为94%),以及良好的速率能力(最高2 C速率)。此外,代替爆炸性和高反应性的钾金属电极,其由电化学钾浸渍的硬碳和K的全电池2小号X(5≤ X ≤6)构造了阴极电解液,以证明建立安全的不含金属钾的K–S电池系统的可行性。
更新日期:2018-01-29
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