Synthesis and Properties of Tetranitro-Substituted Adamantane Derivatives.,ChemPlusChem

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Synthesis and Properties of Tetranitro-Substituted Adamantane Derivatives.
ChemPlusChem ( IF 3.0 ) Pub Date : 2018-01-01 , DOI: 10.1002/cplu.201700542
Thomas M Klapötke ₁ , Burkhard Krumm ₁ , Anna Widera ₁

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Several new nitro-substituted adamantane compounds based on adamantane-1,3,5,7-tetrol were synthesized and the previously only briefly reported tetranitrate was reinvestigated. The materials were completely characterized by spectroscopic methods including some by X-ray diffraction. The energetic properties, thermal stabilities, and sensitivities of the nitrocarbamate, nitrocarbamate salt, and nitrate were determined and compared to current composites in terms of potential high-energy dense oxidizers (HEDOs). Furthermore, the enthalpies of all compounds were calculated, and their energetic performances investigated by using the EXPLO5 code.

中文翻译：

四硝基取代的金刚烷衍生物的合成和性质。

合成了几种新的基于金刚烷-1,3,5,7-四醇的硝基取代的金刚烷化合物，并对先前仅简要报道的四硝酸盐进行了重新研究。通过光谱方法对材料进行了完全表征，包括通过X射线衍射的一些方法。确定了硝酸氨基甲酸酯，硝酸氨基甲酸酯盐和硝酸盐的能量性质，热稳定性和敏感性，并根据潜在的高能致密氧化剂（HEDOs）与目前的复合材料进行了比较。此外，使用EXPLO5代码计算了所有化合物的焓，并研究了它们的能量性能。

更新日期：2018-01-30

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