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Concise synthesis of ketoallyl sulfones through an iron-catalyzed sequential four-component assembly
Green Chemistry ( IF 9.3 ) Pub Date : 2018-01-24 00:00:00 , DOI: 10.1039/c7gc03719h Fuhong Xiao 1, 2, 3, 4, 5 , Chao Liu 1, 2, 3, 4, 5 , Dahan Wang 1, 2, 3, 4, 5 , Huawen Huang 1, 2, 3, 4, 5 , Guo-Jun Deng 1, 2, 3, 4, 5
Green Chemistry ( IF 9.3 ) Pub Date : 2018-01-24 00:00:00 , DOI: 10.1039/c7gc03719h Fuhong Xiao 1, 2, 3, 4, 5 , Chao Liu 1, 2, 3, 4, 5 , Dahan Wang 1, 2, 3, 4, 5 , Huawen Huang 1, 2, 3, 4, 5 , Guo-Jun Deng 1, 2, 3, 4, 5
Affiliation
A three starting material four component reaction (3SM-4CR) strategy is described to prepare β-acyl allylic sulfones from methyl ketones, sodium sulfinates and dimethylacetamide (DMA) in an iron-catalyzed oxidative system. In this process, DMA was used as a dual synthon to provide two carbons. A broad range of functional groups were tolerated in this reaction system.
中文翻译:
通过铁催化的顺序四组分组装反应合成酮基烯丙基砜
描述了一种在铁催化氧化体系中由甲基酮,亚磺酸钠和二甲基乙酰胺(DMA)制备β-酰基烯丙基砜的三原料四组分反应(3SM-4CR)策略。在此过程中,DMA被用作双重合成子以提供两个碳。在该反应系统中可以容忍各种各样的官能团。
更新日期:2018-03-06
中文翻译:
通过铁催化的顺序四组分组装反应合成酮基烯丙基砜
描述了一种在铁催化氧化体系中由甲基酮,亚磺酸钠和二甲基乙酰胺(DMA)制备β-酰基烯丙基砜的三原料四组分反应(3SM-4CR)策略。在此过程中,DMA被用作双重合成子以提供两个碳。在该反应系统中可以容忍各种各样的官能团。