Concise synthesis of ketoallyl sulfones through an iron-catalyzed sequential four-component assembly,Green Chemistry

当前位置： X-MOL 学术 › Green Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Concise synthesis of ketoallyl sulfones through an iron-catalyzed sequential four-component assembly
Green Chemistry ( IF 9.8 ) Pub Date : 2018-01-24 00:00:00 , DOI: 10.1039/c7gc03719h
Fuhong Xiao _{1,

2,

3,

4,

5} , Chao Liu _{1,

2,

3,

4,

5} , Dahan Wang _{1,

2,

3,

4,

5} , Huawen Huang _{1,

2,

3,

4,

5} , Guo-Jun Deng _{1,

2,

3,

4,

5}

Affiliation

A three starting material four component reaction (3SM-4CR) strategy is described to prepare β-acyl allylic sulfones from methyl ketones, sodium sulfinates and dimethylacetamide (DMA) in an iron-catalyzed oxidative system. In this process, DMA was used as a dual synthon to provide two carbons. A broad range of functional groups were tolerated in this reaction system.

中文翻译：