We have grown hierarchical structure of bismuth oxycloride (BiOCl) on SrO‐Bi₂O₃‐B₂O₃ (SBBO) transparent glass‐ceramic. SBBO glass‐ceramics were fabricated via conventional melt‐quenching technique while BiOCl was grown by etching the glass via HCl. Enhanced visible light driven photocatalytic activity and increasing hydrophobic feature were observed on BiOCl grown SBBO than as‐quenched SBBO glass‐ceramics. Contact angle analysis showed maximum contact angle of 130.7° on the surface of most BiOCl grown SBBO glass‐ceramic. Furthermore, under visible light illumination water contact angle decreased from 130.7° to 30.8°. Such photo‐induced hydrophilicity and catalytic performance in translucent glass‐ceramics lead self‐cleaning applications.

中文翻译：

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BiOCl在用于自清洁应用的SrO-Bi2O3-B2O3玻璃陶瓷上的分层生长

我们已经在SrO‐Bi ₂ O ₃ ‐ B ₂ O ₃上增长了氧氯铋（BiOCl）的层次结构（SBBO）透明玻璃陶瓷。SBBO玻璃陶瓷是通过传统的熔融淬火技术制造的，而BiOCl是通过用HCl蚀刻玻璃而生长的。与骤冷的SBBO玻璃陶瓷相比，在BiOCl生长的SBBO上观察到了增强的可见光驱动的光催化活性和增强的疏水性。接触角分析显示，在大多数BiOCl生长的SBBO玻璃陶瓷表面上的最大接触角为130.7°。此外，在可见光照射下，水的接触角从130.7°减小到30.8°。在半透明玻璃陶瓷中，这种光诱导的亲水性和催化性能可导致自清洁应用。