Organic–inorganic coating has been desirable for practical applications in electrochemistry and analytical science. Up to this investigation, a report of a “flowerlike” structure made from organic components has been rarely reported. Here, we proposed a novel strategy to fabricate the flowerlike hybrid coating through the combination of plasma electrolysis and dip chemical coating in which 4-[4-(phyenylazo)phenylazo]-o-cresol (PPC) was used as the organic component. The formation of organic molecules was initiated effectively on the rough inorganic coating by the charge transfer complexes which facilitate the nucleation of organic molecules. The quantum chemical analysis was implemented to discuss the binding sites activated by PPC. The electrochemical resistance was improved significantly due to the synergistic influences of the inorganic coating via plasma electrolysis and organic coating via self-assembly of PPC.

中文翻译：

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花状有机-无机涂层，通过有机化合物的自组装，具有出色的耐腐蚀性

有机-无机涂层在电化学和分析科学的实际应用中是理想的。截至本次调查，几乎没有关于有机成分制成的“花状”结构的报道。在这里，我们提出了一种通过等离子电解和浸涂化学涂层的组合来制造花状杂化涂层的新策略，其中4- [4-（phyenylazoazophenylphenylazo]] o-甲酚（PPC）用作有机组分。有机分子的形成是通过促进有机分子成核的电荷转移络合物有效地在粗糙的无机涂层上引发的。进行量子化学分析以讨论由PPC激活的结合位点。由于无机涂层通过等离子体电解和有机涂层通过PPC的自组装的协同影响，电化学电阻得到了显着提高。