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Oxycyanation of Vinyl Ethers with 2,2,6,6-Tetramethyl-N-oxopiperidinium Enabled by Electron Donor–Acceptor Complex
Organic Letters ( IF 4.9 ) Pub Date : 2018-01-18 00:00:00 , DOI: 10.1021/acs.orglett.7b03858
Jia-Li Liu 1 , Ze-Fan Zhu 1 , Feng Liu 1
Affiliation  

An efficient and mild oxycyanation of vinyl ethers with 2,2,6,6-tetramethyl-N-oxopiperidinium and TMSCN is described. The mechanistic studies indicated that the formation of an electron donor–acceptor complex and subsequent single-electron-transfer process could be involved in the reaction.

中文翻译:

电子给体-受体配合物实现的2,2,6,6-四甲基-N-氧代哌啶鎓对乙烯基醚的氧氰化作用

描述了用2,2,6,6-四甲基-N-氧代哌啶鎓和TMSCN对乙烯基醚进行有效且温和的氧氰化。机理研究表明,该反应可能涉及电子给体-受体配合物的形成以及随后的单电子转移过程。
更新日期:2018-01-18
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