Visible-Light-Driven Silver-Catalyzed One-Pot Approach: A Selective Synthesis of Diaryl Sulfoxides and Diaryl Sulfones,Organic Letters

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Visible-Light-Driven Silver-Catalyzed One-Pot Approach: A Selective Synthesis of Diaryl Sulfoxides and Diaryl Sulfones
Organic Letters ( IF 4.9 ) Pub Date : 2018-01-18 00:00:00 , DOI: 10.1021/acs.orglett.7b03901
Dong Hyuk Kim ₁ , Juyoung Lee ₁ , Anna Lee ₁

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An efficient one-pot approach for the synthesis of diaryl sulfoxides and diaryl sulfones using aryl thiols and aryl diazonium salts was developed. The use of a visible-light-driven silver catalysis and the subsequent singlet-oxygen-induced oxidation enabled selective synthesis of sulfoxides and sulfones in the absence of a photocatalyst. The reactions were carried out under mild reaction conditions; the desired products were obtained under air atmosphere at room temperature.

中文翻译：

可见光驱动的银催化一锅法：二芳基亚砜和二芳基砜的选择性合成

开发了一种有效的一锅法，用于使用芳基硫醇和芳基重氮盐合成二芳基亚砜和二芳基砜。使用可见光驱动的银催化以及随后的单线态氧诱导的氧化使得能够在不存在光催化剂的情况下选择性合成亚砜和砜。反应在温和的反应条件下进行。在室温和空气气氛下获得所需产物。

更新日期：2018-01-18

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