Homoleptic U(iii) and U(iv) amidate complexes†‡,Dalton Transactions

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Homoleptic U(iii) and U(iv) amidate complexes†‡
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-01-18 00:00:00 , DOI: 10.1039/c7dt04813k
M. D. Straub _{1,

2,

3,

4,

5} , S. Hohloch _{1,

2,

3,

4,

5} , S. G. Minasian _{3,

4,

5,

6} , J. Arnold _{1,

2,

3,

4,

5}

Affiliation

The syntheses of the first homoleptic U(III) and U(IV) amidate complexes are described. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(III) complex to eight in the U(IV) complex in the solid state structures.

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