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AIBN‐Initiated Denitrative Cross‐Coupling Reactions of β‐Nitrostyrenes with Sulfonyl Hydrazides/Disulfides: A Metal‐free Approach towards Vinyl Sulfones
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-01-18 , DOI: 10.1002/ajoc.201700632 Saurabh Kumar 1 , Rahul Singh 1 , Krishna Nand Singh 1
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-01-18 , DOI: 10.1002/ajoc.201700632 Saurabh Kumar 1 , Rahul Singh 1 , Krishna Nand Singh 1
Affiliation
A practical approach involving denitrative coupling of β‐nitrostyrenes and sulfonyl hydrazides/disulfides by AIBN (azobisisobutyronitrile) has been developed to accomplish the synthesis of vinyl sulfones. The method employs easily accessible starting materials, and is endowed with a broad substrate scope and functional group tolerance.
中文翻译:
AIBN引发的β-硝基苯乙烯与磺酰肼/二硫化物的反硝化交叉偶联反应:一种无金属的乙烯基砜方法
已开发出一种实用的方法,涉及通过AIBN(偶氮二异丁腈)将β-硝基苯乙烯与磺酰肼/二硫化物进行反硝化偶联,以完成乙烯基砜的合成。该方法采用易于获得的起始原料,并具有广泛的底物范围和官能团耐受性。
更新日期:2018-01-18
中文翻译:
AIBN引发的β-硝基苯乙烯与磺酰肼/二硫化物的反硝化交叉偶联反应:一种无金属的乙烯基砜方法
已开发出一种实用的方法,涉及通过AIBN(偶氮二异丁腈)将β-硝基苯乙烯与磺酰肼/二硫化物进行反硝化偶联,以完成乙烯基砜的合成。该方法采用易于获得的起始原料,并具有广泛的底物范围和官能团耐受性。