Supramolecular Polymers: Tunable Energy Landscapes to Control Pathway Complexity in Self‐Assembled N‐Heterotriangulenes: Living and Seeded Supramolecular Polymerization (Small 3/2018),Small

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Supramolecular Polymers: Tunable Energy Landscapes to Control Pathway Complexity in Self‐Assembled N‐Heterotriangulenes: Living and Seeded Supramolecular Polymerization (Small 3/2018)
Small ( IF 13.0 ) Pub Date : 2018-01-18 , DOI: 10.1002/smll.201870012
Jorge S. Valera ₁ , Rafael Gómez ₁ , Luis Sánchez ₁

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In article 1702437, Luis Sánchez and co‐workers describe the synthesis and self‐assembly of N‐heterotriangulenes 1–3 with a tunable energy landscape. Seeded and living supramolecular polymerizations are realized through the autocatalytic transformation of the metastable monomeric units, as well as the two competing off‐ and on‐pathway aggregates. The relevance of controlling pathway complexity in self‐assembling units, and new avenues for the investigation of complex and functional supramolecular structures are shown. The authors acknowledge Dr. J. Calbo for his generous help in the preparation of the cover.

中文翻译：

超分子聚合物：可调节的能量格局以控制自组装N-杂三烯的途径复杂性：超分子聚合和种子聚合（Small 3/2018）

路易斯·桑切斯（LuisSánchez）和他的同事们在文章1702437中描述了具有可调整能量分布的N-杂三烯酮1-3的合成和自组装。种子和活性超分子聚合是通过亚稳态单体单元的自动催化转化，以及两种竞争的路途和路途聚集体而实现的。显示了在自组装单元中控制途径复杂性的相关性，以及研究复杂和功能性超分子结构的新途径。作者感谢J. Calbo博士在准备封面方面的慷慨帮助。

更新日期：2018-01-18

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