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Rewiring Chemical Networks Based on Dynamic Dithioacetal and Disulfide Bonds
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-02-05 , DOI: 10.1002/chem.201705654
A. Gastón Orrillo 1 , Agustina La-Venia 2 , Andrea M. Escalante 1 , Ricardo L. E. Furlan 1, 3
Affiliation  

The control of the connectivity between nodes of synthetic networks is still largely unexplored. To address this point we take advantage of a simple dynamic chemical system with two exchange levels that are mutually connected and can be activated simultaneously or sequentially. Dithioacetals and disulfides can be exchanged simultaneously under UV light in the presence of a sensitizer. Crossover reactions between both exchange processes produce a fully connected chemical network. On the other hand, the use of acid, base or UV light connects different nodes allowing network rewiring.

中文翻译:

基于动态二硫缩醛和二硫键的化学网络重布线

合成网络的节点之间的连通性的控制仍在很大程度上未被探索。为了解决这一点,我们利用了一个简单的动态化学系统,该系统具有两个相互连接的交换级,可以同时或顺序激活。二硫缩醛和二硫化物可以在敏化剂存在的情况下在紫外光下同时交换。两种交换过程之间的交叉反应产生了完全连接的化学网络。另一方面,使用酸,碱或紫外线可以连接不同的节点,从而可以进行网络重新布线。
更新日期:2018-02-05
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