Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-01-18 , DOI: 10.1002/anie.201800064 Xuemin Bai,Chuandong Jia,Yanxia Zhao,Dong Yang,Shi-Cheng Wang,Anyang Li,Yi-Tsu Chan,Yao-Yu Wang,Xiao-Juan Yang,Biao Wu
Peripheral templation was used to stabilize an unusual A4L6 tetrahedral cage (A=anion, L=ligand) as reported by C. Jia, B. Wu et al. in their Communication on page 1851. The A4L6 cage can be transformed into an A2L3 helicate in response to different stimuli (change template, concentration, or solvent), with accompanying guest capture and release. This process is illustrated in the picture by the famous Monkey King who has the power to change the shape and size of objects by blowing magic gas. Credits: Cartoon of the Monkey King from http://588ku.com/image/n-13858873.html.
中文翻译:
内部封面:具有客体捕获/释放功能的A4L6四面体阴离子笼和A2L3三重螺旋之间的外围模板调制互变(Angew。Chem。Int。Ed。7/2018)
外围模板被用来稳定一个不寻常的A 4 L 6四面体笼(A =阴离子,L =配体),正如C. Jia,B. Wu等人报道的那样。请参见第1851页的“交流”中的说明。A 4 L 6笼子可以响应不同的刺激(改变模板,浓度或溶剂)而转化为A 2 L 3螺旋体,并伴有客体捕获和释放。照片中著名的猴子王(Monkey King)说明了这一过程,他有能力通过吹入魔术气体来改变物体的形状和大小。现金:从孙悟空的卡通http://588ku.com/image/n-13858873.html。