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Mineralization of sulfolane in aqueous solutions by Ozone/CaO2 and Ozone/CaO with potential for field application
Chemosphere ( IF 8.1 ) Pub Date : 2018-01-18 , DOI: 10.1016/j.chemosphere.2018.01.072
Maryam Izadifard , Gopal Achari , Cooper H. Langford

Mineralization of sulfolane in aqueous systems by CaO2/O3 and CaO/O3 was investigated in this study. If 1.6 g/L of oxidants (CaO2 and CaO) were used along with 5 L/min of O3 in a batch reactor, degradation of sulfolane followed a pseudo-first order kinetics model. Both sulfolane and TOC were totally removed in less than 40 and 150 min respectively. For these treatments, the pH of the aqueous solutions was above 11, which made O3 more effective in removing sulfolane. However, the high pH of the solution didn't improve TOC removal. For TOC removal the presence of CaO2 and CaO was necessary.

Once these conditions were optimised in the lab, field experiments were designed and evaluated to treat contaminated ground water samples. The field tests were successful in mineralization of sulfolane within a reasonable time (4 h). Sulfolane degradation took 150 min in these experiments. The pH of the water samples were brought to near neutral (pH = 6.5) by bubbling CO2.



中文翻译:

臭氧/ CaO 2和臭氧/ CaO在水溶液中环丁砜的矿化作用具有潜在的现场应用潜力

在这项研究中,研究了环丁砜中CaO 2 / O 3和CaO / O 3的矿化作用。如果在间歇反应器中使用1.6 g / L的氧化剂(CaO 2和CaO)以及5 L / min的O 3,则环丁砜的降解遵循拟一级动力学模型。环丁砜和TOC分别在不到40分钟和150分钟内被完全去除。对于这些处理,水溶液的pH高于11,这使得O 3在除去环丁砜中更有效。但是,溶液的高pH值并不能提高TOC的去除率。为了去除TOC,必须存在CaO 2和CaO。

一旦在实验室中优化了这些条件,便会设计并评估现场实验,以处理受污染的地下水样品。现场测试成功地在合理的时间内(4小时)使环丁砜矿化。在这些实验中,环丁砜的降解耗时150分钟。通过鼓泡CO 2使水样品的pH值接近中性(pH = 6.5)。

更新日期:2018-01-18
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